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Peculiar structure of the HOOO(super -) anion
- Source :
- Journal of the American Chemical Society. July 17, 2002, Vol. 124 Issue 28, 8462-8470
- Publication Year :
- 2002
-
Abstract
- The HOOO(super -) anion, which can adopt a triplet state (T-1) or a singlet state (S-1), where the former was 9.8 kcal/mol (delta H(298) = 10.3 kcal/mol), which was more stable than the later is reported. The modes of generating S-1 in aqueous solution was discussed, which shows that S-1 represents an important intermediate in ozonation reactions.
- Subjects :
- Ozonization -- Observations
Anions -- Research
Hydrogen -- Research
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 124
- Issue :
- 28
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.123731952