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Characterization of Chlorovinylcobalamin, a putative intermediate in reductive degradation of chlorinated ethylenes
- Source :
- Journal of the American Chemical Society. April 16, 2003, Vol. 125 Issue 15, p4410, 2 p.
- Publication Year :
- 2003
-
Abstract
- Chlorovinylcobalamin could be generated by reaction of cob(I)alamin with chloroacetylene, a compound detected as an intermediate in the B12-catalyzed dechlorination of perchloroethylene. Return of chlorinated vinylcobalamins to the active form of the catalyst could be achieved through reductive dealkylation promoted by col(I)alamin.
- Subjects :
- Ethylene -- Research
Catalysts -- Usage
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 125
- Issue :
- 15
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.123705550