Back to Search Start Over

Intramolecular reactions of alkynes with furans and electron rich arenas catalyzed by PtCl2: the role of platinum carbenes as intermediates

Authors :
Martin-Matute, Belen
Nevado, Cristina
Cardenas, Diego J.
Echavarren, Antonio M.
Brana, Alfredo F.
Rix, Uwe
Oliveira, Marcos A.
Mendez, Carmen
Salas, Jose A.
Rohr, Jurgen
Source :
Journal of the American Chemical Society. May 14, 2003, Vol. 125 Issue 19, p5757, 10 p.
Publication Year :
2003

Abstract

The intramolecular reaction of furans with alkynes catalyzed by PtCl2 is mechanistically related to that of enynes in polar solvents. The reactivity of intermediate platinum carbenes formed in the PtCl2-catalyzed reactions of alkynes with alkenes or furans.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
19
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.123629519