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NMR and X-ray spectroscopy of sodium-silicon clathrates

Authors :
He, Jiliang
Klug, Dennis D.
Uehara, Kentaro
Preston, Keith F.
Ratcliffe, Christopher I.
Tse, John S.
Source :
Journal of Physical Chemistry B. May 3, 2001, Vol. 105 Issue 17, p3475, 11 p.
Publication Year :
2001

Abstract

The (super 23)Na and (super 29)Si NMR spectra of the sodium-silicon clathrate materials Na(sub 8)Si(sub 46) and Na(sub x)Si(sub 136) are studied in detail. NMR, XPS and XANES results showed an interaction between Na atom and the Si framework of the clathrates.

Details

Language :
English
ISSN :
15206106
Volume :
105
Issue :
17
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry B
Publication Type :
Academic Journal
Accession number :
edsgcl.123614327