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Why does cyclopropene have the acidity of an acetylene but the bond energy of methane?
- Source :
- Journal of the American Chemical Society. Sept 24, 2003, Vol. 125 Issue 38, 11746-11750
- Publication Year :
- 2003
-
Abstract
- Bracketing and equilibrium techniques were used for examining the gas-phase acidity of 3,3-dimethylcyclopropene. The C-H bond energies of 3,3-dimethylcyclopropene differs by 26.1 plusmn 3.8 kcal mol(super -1).
- Subjects :
- Methane -- Research
Hydrogen bonding -- Research
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 125
- Issue :
- 38
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.123560656