Reversible disulfur monoxide (S2O)-forming retro-Diels-Alder reaction: disproportionation of S2O to trithio-ozone (S3) and sulfur dioxide (SO2) and reactivities of S2O and S3

Authors :: Nakayama, Juzo
Aoki, Satoshi
Takayam, Jun
Sakamoto, Akira
Sugihara, Yoshiaki
Ishii, Akihiko
Source :: Journal of the American Chemical Society. July 28, 2004, Vol. 126 Issue 29, p9085, 9 p.
Publication Year :: 2004
Abstract: A new and clean method that yields free S2O by a hetero retro-Diels-Alder reaction is presented. The computational rationalization of the chemical properties of S2O and its disproportionation to SO2 and S3 is described.

Subjects :: Diels-Alder reaction -- Analysis
Sulfur dioxide -- Chemical properties
Sulfur dioxide -- Research
Chemical reactions -- Analysis
Disproportionation
Chemistry

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