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Organmetallic early lanthanide clusters: syntheses and x-ray structures of new monocyclopentadienyl complexes

Authors :
Bonnet, Fanny
Visseaux, Marc
Barbier-Baudry, Denise
Hafid, Abderrafia
Vigier, Estella
Kubicki, Marek M.
Source :
Inorganic Chemistry. June 14, 2004, Vol. 43 Issue 12, p3682, 9 p.
Publication Year :
2004

Abstract

A series of new borohydrido- and chloro-half-lanthanidocenes of early rare earths (Ln = Sm, Nd) were synthesized, bearing the Cp(super *') ligand (Cp(super *') = C5Me4nPr). It is found that pure borohydrido Sm complex undergoes easy opening of BH4 bridges in the presence of THF vapors.

Details

Language :
English
ISSN :
00201669
Volume :
43
Issue :
12
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.122971641