Li -induced sigma-bond metathesis: Aryl for methyl exchange on boron in a methylated monocarbadodecaborate anion

Authors :: Janousek, Zbynek
Lehmann, Uwe
Castulik, Jakub
Cisarova, Ivana
Michl, Josef
Source :: Journal of the American Chemical Society. April 7, 2004, Vol. 126 Issue 13, 4060-4061
Publication Year :: 2004
Abstract: The formal sigma-bond methesis between the B-CH3 bond in position 12 of the lithium monocarbadodecaborate derivative is reported. The Li -induced B-arylation reaction are presently under examination.

Subjects :: Borates -- Research
Metal ions -- Research
Anions -- Research
Chemical bonds -- Research
Methylation -- Research
Methyl groups -- Research
Chemistry

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