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Direct detection of formate ligation in Cytochrome c Oxidase by ATR-FTIR spectroscopy

Authors :
Iwaki, Masayo
Rich, Peter R.
Source :
Journal of the American Chemical Society. March 3, 2004, Vol. 126 Issue 8, 2386-2389
Publication Year :
2004

Abstract

Questions with regards to the binding of formate to the binuclear site of bovine cytochrome c oxidase (CcO) by perfusion-induced attenuated total reflection Fourier transform infrared (ATR-FTIR) are addressed. Data show unequivocally that formate binds in its anionic form despite its binding being electroneutral overall.

Details

Language :
English
ISSN :
00027863
Volume :
126
Issue :
8
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.119432420