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Donor-stabilized cations and imine transfer from N-silylphosphoranimines

Authors :
Rivard, Eric
Huynh, Keith
Lough, Alan J.
Manners, Ian
Source :
Journal of the American Chemical Society. March 3, 2004, Vol. 126 Issue 8, 2286-2287
Publication Year :
2004

Abstract

The reaction between Cl2P=NSiMe3 and Ag[OTf] in the presence of the strong donor 4-(dimethylamino)-pyridine (DMAP) is presented. An immediate formation of a white precipitate (Agcl) was observed by combining these reagents with Ch2Cl2.

Subjects

Subjects :
Chemical compounds -- Analysis
Chemical compounds -- Chemical properties
Silver compounds -- Analysis
Silver compounds -- Chemical properties
Chemical reactions -- Analysis
Chemistry

Details

Language :
English
ISSN :
00027863
Volume :
126
Issue :
8
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.119407318

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