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pH-specific synthesis of a dinuclear vanadium(V)-peroxo-citrate complex in aqueous solutions: pH-dependent linkage, spectroscopic and structural correlations with other aqueous vanadium(V)-peroxo-citrate and non-peroxo

Authors :
Kaliva, M.
Raptopoulou, C.P.
Terzis, A.
Salifoglou, A.
Source :
Inorganic Chemistry. May 3, 2004, Vol. 43 Issue 9, 2895-2905
Publication Year :
2004

Abstract

It is found that Vanadium's insulin mimetic role in biology entails complex interactions with physiological ligands. Efforts to unravel such interactions led to pH-specific redox as well as nonredox reactions of vanadium(III,V) with critic acid and H2O2.

Details

Language :
English
ISSN :
00201669
Volume :
43
Issue :
9
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.119371743