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Unexpected reactivity of PdCl2 and PtCl2 complexes of the unsaturated diphosphine o-Me2TTF(PPh2)2 toward chloride abstraction with thallium triflate
- Source :
- Inorganic Chemistry. May 17, 2004, Vol. 43 Issue 10, 3136-3141
- Publication Year :
- 2004
-
Abstract
- PdCl2 and PtCl2 complexes of the redox active diphosphine P2 have been synthesized, and the palladium one is structurally characterized. It is found that the single crystal x-ray analysis on the resulting compound showed the formation of a dimeric complex salt, formulated as [(dppen)PdCl](sub 2)(OTf)(sub 2).
- Subjects :
- Chemical compounds -- Analysis
Chemical compounds -- Chemical properties
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 43
- Issue :
- 10
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.119353947