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Cobalt(II) dioxygen carriers based on simple diamino ligands: kinetic and ab initio studies

Authors :
Comuzzi, Clara
Melchior, Andrea
Polese, Pierluigi
Portanova, Roberto
Tolazzi, Marilena
Source :
Inorganic Chemistry. Dec 15, 2003, Vol. 42 Issue 25, 8214-8222
Publication Year :
2003

Abstract

The kinetic of the oxygenation reaction of CoL(sub 2)(super 2+) complexes are investigated in dimethyl sulfoxide by means of a UV-vis technique is explained. Ab initio calculations provide insights on the geometrical parameters of all the complexes.

Details

Language :
English
ISSN :
00201669
Volume :
42
Issue :
25
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.119351398