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Tris(bis(trimethylsilyl)amido)samarium: X-ray structure and DFT study
- Source :
- Inorganic Chemistry. Oct 20, 2003, Vol. 42 Issue 21, 6682-6690
- Publication Year :
- 2003
-
Abstract
- Research has been conducted on tris(bis(trimethylsilyl)amido)samarium. The study of this compound has been carried out via the use of density functional theory and X-ray crystallography, and the results have demonstrated that the structure features positional disorder of the metal atom above and below the plane defined by three N donor atoms.
- Subjects :
- Amides -- Chemical properties
Chemistry, Inorganic -- Research
Density functionals -- Usage
Inorganic compounds -- Chemical properties
Inorganic compounds -- Composition
Inorganic compounds -- Structure
Coordination compounds -- Chemical properties
Coordination compounds -- Composition
Coordination compounds -- Structure
Methylation -- Analysis
Samarium -- Chemical properties
Silane -- Chemical properties
X-ray crystallography -- Usage
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 42
- Issue :
- 21
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.112789955