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Complexes of platinum(II) containing neutral and deprotonated 9-methyladenine. Synthesis, X-ray structures, and NMR studies on the cyclic trimer cis-[L (sub)2 Pt{9-MeAd(-H)}] (sub)3 (NO (sub)3) (sub)3 and the dinuclear cis-[L (sub)2 Pt(ONO (sub)2){9-MeAd(-H)}PtL (sub)2](NO (sub)3) (sub)2 (L= PMePh (sub)2)

Authors :
Longato, Bruno
Pasquato, Lucia
Mucci, Adele
Schenetti, Luisa
Zangrando, Ennio
Source :
Inorganic Chemistry. Dec 1, 2003, Vol. 42 Issue 24, 7861-7871
Publication Year :
2003

Abstract

Research has been conducted on dinuclear hydroxo complex cis-[L (sub)2 Pt(ONO (sub)2){9-MeAd(-H)}PtL (sub)2](NO (sub)3) (sub)2, where L is PMePh (sub)2. The authors have demonstrated that this complex deprotonates NH (sub)2 group of 9-methyladenine in solution to produce cis-[L (sub)2 Pt{9-MeAd(-H)}] (sub)3 (NO (sub)3) (sub)3.

Details

Language :
English
ISSN :
00201669
Volume :
42
Issue :
24
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.111976109