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Preparation of benzocyclobutenols by low temperature reaction of ketone enolates with benzynes

Authors :
Tripathy, Sasmita
Reddy, Ranga
Durst, Tony
Source :
Canadian Journal of Chemistry. Sept, 2003, Vol. 81 Issue 9, p997, 6 p.
Publication Year :
2003

Abstract

The reaction of benzynes, generated from halobenzenes with lithium tetramethylpipiperide (LTMP) at-40 to-78 [degrees]C, with ketone enolates affords benzocyclobutenols in fair to good yields. Key words: benzyne, ketone enolates, anthracenes, benzocyclobutenol, alkoxides.

Details

Language :
English
ISSN :
00084042
Volume :
81
Issue :
9
Database :
Gale General OneFile
Journal :
Canadian Journal of Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.110263739