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Reactions of the dirhenium(II) complex Re (sub)2 Cl (sub)4 (mu-dppm) (sub)2 with pyridinecarboxylic acids. Examples of bidentate O,O versus N,O coordination and tridentate O,N,O coordination and structural isomers that contain the pyridine-2,6-dicarboxylate ligand
- Source :
- Inorganic Chemistry. Sept 22, 2003, Vol. 42 Issue 19, 5924-5931
- Publication Year :
- 2003
-
Abstract
- Research has been conducted on pyridine-2-dicarboxylic-, pyridine-2,6-dicarboxylic- and pyridine-2,4-dicarboxylic acids and their salts. The authors demonstrate that these compounds react with triply bonded dirhenium(II) complex is respond to ethanol, and produce unsymmetrical substitution products where N,O represents a chelating pyridine-2-carboxylate ligand.
- Subjects :
- Chemical bonds
Alcohol, Denatured
Alcohol
Salts -- Composition
Ligands
Pyridine
Chemical structure -- Analysis
Coordination compounds -- Composition
Complex compounds -- Composition
Nitrogen
Oxygen
Chlorine
Carboxylic acids
Substitution reactions -- Analysis
Rhenium
Inorganic compounds -- Composition
Chemistry, Inorganic -- Research
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 42
- Issue :
- 19
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.109481190