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Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones

Authors :
Prakash, G. K. Surya
Hu, Jinbo
Olah, George A.
Source :
Journal of Organic Chemistry. May 30, 2003, Vol. 68 Issue 11, 4457-4463
Publication Year :
2003

Abstract

Research has been conducted on tri- and difluoromethylsilanes. The authors describe the preparation of these compounds via the use of magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes.

Details

Language :
English
ISSN :
00223263
Volume :
68
Issue :
11
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.103480717