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Catalysis of the beta-elimination of HF from isomeric 2-fluoroethylpyridines and 1-methyl-2-fluoroethylpyridinium salts. Proton-activating factors and methyl-activating factors as a mechanistic test to distinguish between concerted E2 and E1cb irreversible mechanisms

Authors :
Alunni, Sergio
Laureti, Valeria
Ottavi, Laura
Ruzziconi, Renzo
Source :
Journal of Organic Chemistry. Feb 7, 2003, Vol. 68 Issue 3, 718-725
Publication Year :
2003

Abstract

Research has been conducted on beta-elimination reactions. The mechanism of the base-induced beta-elimination reactions in pyridine ring activated systems with fluorine as a leaving group is described.

Details

ISSN :
00223263
Volume :
68
Issue :
3
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.101433709