Molecular Theory of Electric Double Layers

The electrical double layer describes charge and potential distributions that form at the interface between electrolyte solutions and the surface of an object, and they play a fundamental role in chemical and electrochemical behaviour. Colloid science, electrochemistry, material science, and biology are a few examples where such interfaces play a crucial role. The focus of this book is on the application of modern liquid state theories to the properties of electric double layers, where it demonstrates the ability of statistical mechanical approaches, such as the classical density functional theory, to provide insights and details that will enable a better and more quantitative understanding of electric double layers. The book will be essential reading for advanced students and researchers in interfacial science and its numerous applications. Key FeaturesIncludes both continuum and molecular modelsRelies on modern statistical mechanical approachesSuitable for chemists, physicists, material scientists and engineersOffers a new outlook for fundamental and applied researchers on the basic physics and chemistry of charged interfaces involving electrolytesHelps to advance further research fields as colloid science, electrochemistry, material science, and physical chemistry of electrolytes.