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(E)-3-(2-{2-[1-(3-Hydroxyphenyl)ethylidene]hydrazinyl}-1,3-thiazol-4-yl)-2H-chromen-2-one
- Source :
- Acta Crystallographica Section E, Vol 67, Iss 5, Pp o1072-o1073 (2011)
- Publication Year :
- 2011
- Publisher :
- International Union of Crystallography, 2011.
-
Abstract
- In the title compound, C20H15N3O3S, the thiazole ring is approximately planar, with a maximum deviation of 0.003 (1) Å, and makes dihedral angles of 7.44 (6) and 1.88 (6)° with the hydroxy-substituted phenyl ring and the pyran ring, respectively. The hydroxyl group is disordered over two sets of sites, with an occupancy ratio of 0.567 (3):0.433 (3). In the crystal, the major disorder component molecules are connected via bifurcated (three-centre) O—H...O and C—H...O hydrogen bonds, generating R12(6) motifs and resulting in supramolecular chains along the a axis. In the minor occupancy component, however, molecules are connected via C—H...O hydrogen bonds, forming supramolecular chains along the b axis. Furthermore, the crystal structure is stabilized by π–π interactions between the thiazole rings [centroid–centroid distance = 3.5476 (7) Å].
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 67
- Issue :
- 5
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.fcf605fb60a14483b843feaa96a7334f
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536811012189