Adhesive Joint Degradation Due to Hardener-to-Epoxy Ratio Inaccuracy under Varying Curing and Thermal Operating Conditions

This paper presents the results of an experimental study of adhesive joint strength with consideration of the inaccuracy of the hardener dosage, in the context of evaluating the degradation of joints when used either at ambient or elevated temperatures. The butt joint strength characteristics were assessed for two types of adhesives—rigid and flexible—and two curing scenarios—with and without heat curing. An excess hardener was shown to be significantly more unfavourable than its deficiency, which can ultimately be considered as a recommendation for forming epoxy adhesive joint assemblies. In order to fully understand the relationship between the analysed mechanical properties of the material and the influence of component ratio excesses and heating, a process of fitting basic mathematical models to the obtained experimental data was also performed.