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4,4′-(Ethene-1,2-diyl)dipyridinium 4-[2-(pyridin-4-yl)ethenyl]pyridinium octacyanidomolybdate(V) tetrahydrate
- Source :
- Acta Crystallographica Section E, Vol 69, Iss 3, Pp m132-m132 (2013)
- Publication Year :
- 2013
- Publisher :
- International Union of Crystallography, 2013.
-
Abstract
- The crystal structure of the title compound, (C12H12N2)(C12H11N2)[Mo(CN)8]·4H2O, consists of 4,4′-(ethene-1,2-diyl)dipyridinium and 4-[2-(pyridin-4-yl)ethenyl]pyridinium cations disordered over the same site, an [Mo(CN)8]3− anion and four water molecules of crystallization. The eight-coordinate [Mo(CN)8]3− unit exhibits a slightly distorted square-antiprismatic geometry. In the structure, the cations (crystallographic symmetry, 2) and anions (crystallographic symmetry, 222) are arranged alternately by N—H...O and O—H...N hydrogen bonds, forming layers parallel to the bc plane. These layers are further linked through O—H...N hydrogen bonds, generating a three-dimensional supramolecular network.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 69
- Issue :
- 3
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.f8922fbcdb847dbb7670f6de63c8c79
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536813002985