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1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside

Authors :
Xiaoming Wang
Yonghua Yang
Hongchang Liu
Haoriqinbatu
Runan Tian
Source :
Acta Crystallographica Section E, Vol 68, Iss 3, Pp o635-o635 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

The title compound, C19H19NO10, was obtained from the reaction of α-d-1-bromo-2,3,4-tri-O-acetylxylose with N-hydroxyphthalimide in the presence of potassium carbonate. The asymmetric unit contains two independent molecules, in which the O—CH—O—N torsion angles are 73.0 (4) and 65.0 (4)°. The hexapyranosyl rings adopt chair conformations and the substituent groups are in equatorial positions. In the crystal, molecules are linked by nonclassical C—H...O hydrogen bonds.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
3
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.f6533418d9148e4ae368aa1f04f44c7
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536812004369