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Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide

Authors :
Gunay Z. Mammadova
Elizaveta D. Yakovleva
Gleb M. Burkin
Victor N. Khrustalev
Mehmet Akkurt
Sevim Türktekin Çelikesir
Ajaya Bhattarai
Source :
Acta Crystallographica Section E: Crystallographic Communications, Vol 79, Iss 8, Pp 747-751 (2023)
Publication Year :
2023
Publisher :
International Union of Crystallography, 2023.

Abstract

In the title compound, C25H17N3O5S2, intramolecular π–π interactions [centroid-to-centroid distance = 3.5640 (9) Å] are observed between the furan and benzene rings of the 4-cyanophenyl group. In the crystal, molecules are connected via C—H...O and C—H...N hydrogen bonds, forming layers parallel to the (100) plane. These layers are interconnected by C—H...π interactions and weak van der Waals interactions. Hirshfeld surface analysis indicates that H...H (30.2%), N...H/H...N (22.3%), C...H/H...C (17.9%) and O...H/H...O (15.4%) interactions make the most significant contributions to the crystal packing.

Details

Language :
English
ISSN :
20569890
Volume :
79
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Publication Type :
Academic Journal
Accession number :
edsdoj.f22dd5b0f62405e9c89697e0c51b1ee
Document Type :
article
Full Text :
https://doi.org/10.1107/S2056989023006254