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Novel Synthesis Route of Plasmonic CuS Quantum Dots as Efficient Co-Catalysts to TiO2/Ti for Light-Assisted Water Splitting

Authors :
Larissa Chaperman
Samiha Chaguetmi
Bingbing Deng
Sarra Gam-Derrouich
Sophie Nowak
Fayna Mammeri
Souad Ammar
Source :
Nanomaterials, Vol 14, Iss 19, p 1581 (2024)
Publication Year :
2024
Publisher :
MDPI AG, 2024.

Abstract

Self-doped CuS nanoparticles (NPs) were successfully synthesized via microwave-assisted polyol process to act as co-catalysts to TiO2 nanofiber (NF)-based photoanodes to achieve higher photocurrents on visible light-assisted water electrolysis. The strategy adopted to perform the copper cation sulfidation in polyol allowed us to overcome the challenges associated with the copper cation reactivity and particle size control. The impregnation of the CuS NPs on TiO2 NFs synthesized via hydrothermal corrosion of a metallic Ti support resulted in composites with increased visible and near-infrared light absorption compared to the pristine support. This allows an improved overall efficiency of water oxidation (and consequently hydrogen generation at the Pt counter electrode) in passive electrolyte (pH = 7) even at 0 V bias. These low-cost and easy-to-achieve composite materials represent a promising alternative to those involving highly toxic co-catalysts.

Details

Language :
English
ISSN :
20794991
Volume :
14
Issue :
19
Database :
Directory of Open Access Journals
Journal :
Nanomaterials
Publication Type :
Academic Journal
Accession number :
edsdoj.f10c1916f9f64a5295d6e5b60c87e51e
Document Type :
article
Full Text :
https://doi.org/10.3390/nano14191581