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catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2O3:O1] sesquihydrate]

Authors :
Xiang-Qian Fang
Shan Gao
Seik Weng Ng
Source :
Acta Crystallographica Section E, Vol 68, Iss 6, Pp m721-m721 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

The 1,10-phenanthroline-chelated CoII atom in the polymeric title compound, {[Co(C7H4O6S)(C12H8N2)(H2O)2]·1.5H2O}n, is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water molecules in a trans-CoN2O4 octahedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O—H...O hydrogen bonds into a three-dimensional network.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
6
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.bd414a5cb8694a52b215406b043713c0
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536812018752