ZIF‐Derived Co3O4 Nanoflake Arrays Decorated Nickel Foams as Stable Hosts for Dendrite‐Free Li Metal Anodes

Developing high‐performance anode current collectors with three‐dimensional structure and lithiophilic layers is of great importance to further advance the application of lithium metal batteries. However, relatively few research has focused on the transition of substrate and the intrinsic structure stability after electrodeposition of lithium on substrates, which leads to an incomplete understanding of the behavior of lithium deposition. Herein, a lithium metal anodes host with a highly stable and 3D structure has been effectively produced through in situ development of nanoflake arrays embedded with Co3O4 obtained from ZIF on nickel foams (Co3O4‐NF). And the actual lithium deposition sites and lithium deposition process on Co3O4‐NF are elucidated via a combination of characterization techniques and electrochemical analytical methods. Consequently, the resulting Co3O4‐NF@Li anodes could effectively inhibit lithium dendrite formation and mitigate volume expansion, demonstrating a significantly extended and consistent lifespan of 800 cycles (1600 h) at 1 mA cm−2 with low overpotential and insignificant voltage fluctuation for the process of lithium stripping and plating in symmetric cells. Herein, it is aimed to examine the transitions of metal oxides as a lithiophilic site for the lithium metal anode. It offers novel perspectives and approaches for the design of dendrite‐free lithium metal anodes.