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(1,2,3,4-Tetrahydroisoquinoline-2-carbodithioato-κ2S,S′)(thiocyanato-κN)(triphenylphosphane)nickel(II)

Authors :
P. Valarmathi
S. Thirumaran
S. Selvanayagam
Source :
Acta Crystallographica Section E, Vol 67, Iss 12, Pp m1882-m1882 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

The NiII atom in the mononuclear title compound, [Ni(C10H10NS2)(NCS)(C18H15P)], exists within a S2PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni—S bond lengths support the less effective trans effect of SCN− over PPh3.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
12
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.bca1a500e694a4f930b76b949acefc0
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811050550