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2,2′-(Propane-1,3-diyl)bis(2H-indazole)

Authors :
Saúl Ovalle
Sylvain Bernès
Nancy Pérez Rodríguez
Perla Elizondo Martínez
Source :
Acta Crystallographica Section E, Vol 67, Iss 8, Pp o2144-o2144 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

The title molecule, C17H16N4, is a bis-indazole crystallized in the rare 2H-tautomeric form. Indazole heterocycles are connected by a propane C3 chain, and the molecule is placed on a general position, in contrast to the analogous compound with a central C2 ethane bridge, which was previously found to be placed on an inversion center in the same space group. In the title molecule, indazole rings make a dihedral angle of 60.11 (7)°, and the bridging alkyl chain displays a trans conformation, resulting in a W-shaped molecule. In the crystal, molecules interact weakly through π–π contacts between inversion-related pyrazole rings, with a centroid–centroid separation of 3.746 (2) Å.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.b80104a02e4ec8b0a2cc3467b54da2
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811029011