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Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate

Authors :
Cao-Yuan Niu
Hai-Yan Zhang
Yu-Li Dang
Chun-Hong Kou
Source :
Acta Crystallographica Section E, Vol 65, Iss 9, Pp m1029-m1029 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

In the title compound, [Ag(C14H10N4O)2]CF3CO2, the AgI ion is coordinated by two N atoms of the pyridine rings of two N′-(3-cyanobenzylidene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed via Ag...N interactions [Ag...N = 3.098 (2) and 3.261 (2) Å] from symmetry-related molecules and intermolecular N—H...O hydrogen bonds between CF3CO2− anions and the hydrazone groups of two ligands give rise to chains. Furthermore, there are Ag...O interactions with a separation of 2.765 (2) Å between chains. The F atoms of the CF3CO2− anion are disordered over two sites with refined occupancies of 0.593 (5) and 0.407 (5).

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
9
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.b77fbc6cafc841c193af12fe62dc5295
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809029183