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Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate
- Source :
- Acta Crystallographica Section E, Vol 65, Iss 9, Pp m1029-m1029 (2009)
- Publication Year :
- 2009
- Publisher :
- International Union of Crystallography, 2009.
-
Abstract
- In the title compound, [Ag(C14H10N4O)2]CF3CO2, the AgI ion is coordinated by two N atoms of the pyridine rings of two N′-(3-cyanobenzylidene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed via Ag...N interactions [Ag...N = 3.098 (2) and 3.261 (2) Å] from symmetry-related molecules and intermolecular N—H...O hydrogen bonds between CF3CO2− anions and the hydrazone groups of two ligands give rise to chains. Furthermore, there are Ag...O interactions with a separation of 2.765 (2) Å between chains. The F atoms of the CF3CO2− anion are disordered over two sites with refined occupancies of 0.593 (5) and 0.407 (5).
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 65
- Issue :
- 9
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.b77fbc6cafc841c193af12fe62dc5295
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536809029183