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catena-Poly[[dichloridozinc(II)]-μ-1,4-bis(3-pyridylmethyl)piperazine]

Authors :
Robert L. LaDuca
Aaron M. Hardy
Source :
Acta Crystallographica Section E, Vol 65, Iss 5, Pp m537-m537 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

In the title compound, [ZnCl2(C16H20N4)]n, tetrahedrally coordinated divalent Zn atoms are ligated by two Cl atoms and two N-donor atoms from two 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligands. The tethering 3-bpmp ligands promote the formation of [ZnCl2(3-bpmp)]n chains situated parallel to (overline{1}02). These chains aggregate via C—H...Cl interactions to form supramolecular layers, which in turn stack to construct the three-dimensional crystal structure.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
5
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.b52e42730f25479f87c72a4afbd1357e
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809013877