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{Bis[2-(diphenylphosphanyl)phenyl] ether-κ2P,P′}(1,1′-dibenzyl-1H,1′H-4,4′bi-1,2,3-triazole-κ2N3,N3′)copper(I) hexafluoridophosphate dichloromethane hemisolvate

Authors :
Uwe Monkowius
Stefan Ritter
Burkhard König
Hartmut Yersin
Manfred Zabel
Source :
Acta Crystallographica Section E, Vol 64, Iss 1, Pp m195-m195 (2008)
Publication Year :
2008
Publisher :
International Union of Crystallography, 2008.

Abstract

In the crystal structure of the title compound, [Cu(C18H16N6)(C36H28OP2)]PF6·0.5CH2Cl2 or [Cu(DPEPhos)(Bn-bta)]PF6·0.5CH2Cl2 {DPEPhos = bis[(diphenylphosphanyl)phenyl] ether and Bn-bta = 1,1′-dibenzyl-1H,1′H-4,4′-bi-1,2,3triazole}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetrahedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
64
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.b42ac33666fe4f1d8ec439c91504c01f
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536807066342