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Bis(ethanamidinium) (1,10-phenanthroline-2,9-dicarboxylato)manganate(II) heptahydrate

Authors :
Wen-Dong Song
Hong-Bo Wang
Yan-Li Miao
Source :
Acta Crystallographica Section E, Vol 69, Iss 1, Pp m10-m11 (2013)
Publication Year :
2013
Publisher :
International Union of Crystallography, 2013.

Abstract

In the title complex, (C2H7N2)2[Mn(C14H6N2O4)2]·7H2O, the MnII atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxylate ligands in a distorted dodecahedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional supramolecular structure is formed through N—H...O and O—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.553 (2) Å].

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
69
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.b325b7ac09c04593b136dc978a992a23
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536812048350