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Efficient, Solvent-Free Oxidation of Organic Compounds with Potassium Dichromate in the Presence of Lewis Acids

Authors :
Abol-Hassan Adibi
Majid M. Sadeghi
Iraj Mohammadpoor-Baltork
Source :
Molecules, Vol 6, Iss 11, Pp 900-908 (2001)
Publication Year :
2001
Publisher :
MDPI AG, 2001.

Abstract

The synthetic utility of potassium dichromate in the presence of Lewis acids under solid phase conditions is described. This reagent efficiently oxidizes alcohols, acyloins, oximes and semicarbazones to their corresponding carbonyl compounds, while trimethylsilyl and tetrahydropyranyl ethers, ethylene acetals and ketals undergo oxidative deprotection to produce carbonyl compounds efficiently.

Details

Language :
English
ISSN :
61100900 and 14203049
Volume :
6
Issue :
11
Database :
Directory of Open Access Journals
Journal :
Molecules
Publication Type :
Academic Journal
Accession number :
edsdoj.b3170d085cca43aa9e2cbc3f660273ae
Document Type :
article
Full Text :
https://doi.org/10.3390/61100900