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(Z)-Methyl 4-({3-[(2,5-dioxoimidazolidin-4-ylidene)methyl]-1H-indol-1-yl}methyl)benzoate

Authors :
Narsimha Reddy Penthala
Thirupathi Reddy Yerram Reddy
Sean Parkin
Peter A. Crooks
Source :
Acta Crystallographica Section E, Vol 65, Iss 1, Pp o62-o63 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

In the title compound, C21H17N3O4, pairs of molecules form a planar[maximum deviation 0.0566 (9) Å] centrosymmetric imidazole dimer via two N—H...O hydrogen bonds. These dimeric units are linked by further N—H...O hydrogen bonds between the ester carbonyl group and the imidazolidine ring, formiing chains parallel to the c-axis direction. In addition, there are π–π stacking interactions between the planar imidazole pairs, with an interplanar spacing of 3.301 (2) Å. There is a double bond with Z geometry connecting the imidazolidine and indole units.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
1
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.b1c09dcc63e45989ab255d94d5b9974
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536808041020