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Aquabis(1H-imidazole-κN3)bis(4-methylbenzoato-κ2O,O′)cadmium(II)
- Source :
- Acta Crystallographica Section E, Vol 64, Iss 5, Pp m714-m715 (2008)
- Publication Year :
- 2008
- Publisher :
- International Union of Crystallography, 2008.
-
Abstract
- In the title compound, [Cd(C8H7O2)2(C3H4N2)2(H2O)], the CdII atom is coordinated by four carboxylate O atoms from two bidentate chelating 4-methylbenzoate ligands, two N atoms from two imidazole ligands and one water molecule in a distorted pentagonal bipyramidal geometry. Intermolecular O—H...O hydrogen bonds between the coordinated water molecule and the carboxylate O atoms of 4-methylbenzoate lead to an infinite chain. These chains are further self-assembled into a two-dimensional layer through N—H...O hydrogen bonds between the imidazole ligands and carboxylate groups. One of the imidazole ligands is disordered over two positions with site-occupancy factors of 0.737 (4) and 0.263 (4).
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 64
- Issue :
- 5
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.b104cce3eff14f5586e6626ed47de258
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536808011331