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Aquabis(1H-imidazole-κN3)bis(4-methylbenzoato-κ2O,O′)cadmium(II)

Authors :
Xiang-Hu Huang
Li-Li Ji
Wen-Dong Song
Source :
Acta Crystallographica Section E, Vol 64, Iss 5, Pp m714-m715 (2008)
Publication Year :
2008
Publisher :
International Union of Crystallography, 2008.

Abstract

In the title compound, [Cd(C8H7O2)2(C3H4N2)2(H2O)], the CdII atom is coordinated by four carboxylate O atoms from two bidentate chelating 4-methylbenzoate ligands, two N atoms from two imidazole ligands and one water molecule in a distorted pentagonal bipyramidal geometry. Intermolecular O—H...O hydrogen bonds between the coordinated water molecule and the carboxylate O atoms of 4-methylbenzoate lead to an infinite chain. These chains are further self-assembled into a two-dimensional layer through N—H...O hydrogen bonds between the imidazole ligands and carboxylate groups. One of the imidazole ligands is disordered over two positions with site-occupancy factors of 0.737 (4) and 0.263 (4).

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
64
Issue :
5
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.b104cce3eff14f5586e6626ed47de258
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536808011331