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Bis[benzyl 3-(3-phenylprop-2-enylidene)dithiocarbazato-κ2N3,S]cadmium

Authors :
M. S. Reza
M. A. A. A. A. Islam
M. T. H. Tarafder
M. C. Sheikh
E. Zangrando
Source :
Acta Crystallographica Section E, Vol 68, Iss 7, Pp m976-m977 (2012)
Publication Year :
2012
Publisher :
International Union of Crystallography, 2012.

Abstract

In the title complex, [Cd(C17H15N2S2)2], the CdII ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bisphenoidal. The two deprotonated Schiff base ligands chelate the CdII ion through the azomethine N and the thiolate S atom. The dihedral angle between the two chelating ligands is 84.01 (9)°. Weak intermolecular C—H...S interactions lead to the formation of chains along the c axis.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
68
Issue :
7
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.9e4b433ce2b4408aa98f0e8d7deec123
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536812028127