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(R)-(+)-2-{[(3-Methyl-4-nitropyridin-2-yl)methyl]sulfinyl}-1H-benzimidazoleDRL-IPD Communication No. IPDO-IPM-00262.

Authors :
Manne Naga Raju
Neelam Uday Kumar
Naveenkumar Kolla
Rakeshwar Bandichhor
Peddy Vishweshwar
Source :
Acta Crystallographica Section E, Vol 67, Iss 8, Pp o2190-o2190 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

The title compound, C14H12N4O3S, is an intermediate of Dexlansoprazole, a proton pump inhibitor (PPI) mainly developed for anti-ulcer activity. The absolute configuration of the title compound was determined as R. The crystal structure reveals that the molecules form chains along the b axis through N—H...N and C—H...O hydrogen-bonded dimers. These chains are connected via weak C—H...O hydrogen bonds.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
8
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.9d2f1d926a0b4ff8bc7b270a45b39406
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811029990