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(η6-Benzene)dichlorido(chlorodicyclohexylphosphane-κP)ruthenium(II) chloroform monosolvate
- Source :
- Acta Crystallographica Section E, Vol 70, Iss 7, Pp m255-m255 (2014)
- Publication Year :
- 2014
- Publisher :
- International Union of Crystallography, 2014.
-
Abstract
- The title compound, [RuCl2(η6-C6H6)(C12H22ClP)]·CHCl3, was prepared by reaction of [RuCl2(η6-C6H6)]2 with chlorodicyclohexylphosphane in CHCl3 at 323 K under argon. The RuII atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru—P bond length of 2.3247 (4) Å. Both cyclohexyl rings at the P atom adopt a chair conformation. In the crystal, the RuII complex molecule and the chloroform solvent molecule are linked by a bifurcated C—H...(Cl,Cl) hydrogen bond. Intramolecular C—H...Cl hydrogen bonds are also observed.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 70
- Issue :
- 7
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.9cd85d3e0394b5da71769cf41391be2
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536814012975