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Construction of model for estimating rate constant of SCR reaction over hydrothermally aged Cu-CHA catalyst

Authors :
Hiroshi MATSUDA
Satoshi SAKAIDA
Kotaro TANAKA
Mitsuru KONNO
Atsuko TOMITA
Takeshi MIKI
Akira OBUCHI
Source :
Nihon Kikai Gakkai ronbunshu, Vol 88, Iss 909, Pp 21-00388-21-00388 (2022)
Publication Year :
2022
Publisher :
The Japan Society of Mechanical Engineers, 2022.

Abstract

Based on the changes of catalyst properties, a model was constructed to estimate the rate constants of Standard-SCR, NH3 oxidation, and NO oxidation reactions over hydrothermally aged Cu-CHA catalyst. Moreover, the rate constants obtained by the constructed model were applied to the model for estimating NOx conversion over fresh catalyst constructed in previous studies, and the NOx conversion over hydrothermally aged catalyst was estimated. As a result, the calculated NOx conversion over hydrothermally aged Cu-CHA catalyst was in good agreement with the experimental results.

Details

Language :
Japanese
ISSN :
21879761
Volume :
88
Issue :
909
Database :
Directory of Open Access Journals
Journal :
Nihon Kikai Gakkai ronbunshu
Publication Type :
Academic Journal
Accession number :
edsdoj.9b4543c4012841cabe08f55824b16b4f
Document Type :
article
Full Text :
https://doi.org/10.1299/transjsme.21-00388