Back to Search Start Over

Poly[(μ2-2-hydroxy-2-methylpropionato-κ3O1,O2:O1′)(μ2-2-hydroxy-2-methylpropionato-κ2O1:κO1′)dioxidouranium(VI)]

Authors :
Takashi Yoshimura
Hidetoshi Kikunaga
Atsushi Shinohara
Source :
Acta Crystallographica Section E, Vol 65, Iss 4, Pp m355-m356 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

In the title compound, [UO2(C4H7O3)2]n, the dioxouranium(VI) units are linked by 2-hydroxy-2-methylpropionate ligands into a honeycomb structure. The U atom is seven-coordinate in a pentagonal-bipyramidal geometry. The uncoordinated hydroxy groups of the 2-hydroxy-2-methylpropionate ions interact with the O atom of the uranyl and with the coordinated hydroxy group of an adjacent 2-hydroxy-2-methylpropionate ion through O—H...O hydrogen bonds.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
4
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.9b3abc2758a4d5ab544c0e64aaed68d
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809006059