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Calculating thermodynamic properties of chain-like molecular fluid mixtures from prediction model(链状分子流体混合物热力学性质的预测模型)
- Source :
- Zhejiang Daxue xuebao. Lixue ban, Vol 28, Iss 5, Pp 517-525 (2001)
- Publication Year :
- 2001
- Publisher :
- Zhejiang University Press, 2001.
-
Abstract
- 本文在张秉坚[1]改进Barker-Henderson微扰理论的基础上，将理论推广应用到链状分子流体混合物热力学性质的计算.推导过程中采用了Wertheim[2]等人的链成键理论和类似Hino-Prausnitz[3]的流体混合法则，导出了链状方阱势分子流体混合物热力学性质的解析表达式.能够计算热力学一致的Helmhotz自由能、压缩因子、内能和恒容热容.计算结果与文献计算机模拟值吻合良好.
Details
- Language :
- Chinese
- ISSN :
- 10089497
- Volume :
- 28
- Issue :
- 5
- Database :
- Directory of Open Access Journals
- Journal :
- Zhejiang Daxue xuebao. Lixue ban
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.96fd5ae409f4a3495977c3f0e788314
- Document Type :
- article