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catena-Poly[sodium-μ2-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ2N:N′-sodium-bis[μ2-bis(trimethylsilyl)azanido-κ2N:N]]
- Source :
- Acta Crystallographica Section E, Vol 68, Iss 12, Pp m1468-m1468 (2012)
- Publication Year :
- 2012
- Publisher :
- International Union of Crystallography, 2012.
-
Abstract
- The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N′,N′-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 68
- Issue :
- 12
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.9554bb7690694235a28f2e66caee49fb
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536812045126