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Poly[[[diaquacobalt(II)]-bis[μ2-1,1′-(butane-1,4-diyl)diimidazole-κ2N3:N3′]] dichloride tetrahydrate]

Authors :
Yu Su
Yan-Jun Hou
Zhi-Zhong Sun
Guang-Feng Hou
Jin-Sheng Gao
Source :
Acta Crystallographica Section E, Vol 65, Iss 4, Pp m370-m371 (2009)
Publication Year :
2009
Publisher :
International Union of Crystallography, 2009.

Abstract

In the title compound, {[Co(C10H14N4)2(H2O)2]Cl2·4H2O}n, the CoII atom and the mid-point of the 1,1′-butane-1,4-diyldiimidazole ligands lie on inversion centers. The CoII atom is six-coordinated in a slightly distorted octahedral environment by four N atoms from four different ligands and by two O atoms from the water molecules. The CoII atoms are bridged by the ligands into a (4,4) net. Adjacent nets are linked to the chloride anions and uncoordinated water molecules via O—H...Cl and O—H...O hydrogen bonds, generating a three-dimensional supramolecular structure.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
65
Issue :
4
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.95086a6e6f6b4815b4743c46dbb4e06b
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536809007478