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(1S,3R,8R)-2,2-Dichloro-3,7,7,10-tetramethyl-11-methylenetricyclo[6.4.0.01,3]dodec-9-ene
- Source :
- IUCrData, Vol 2, Iss 3, p x170421 (2017)
- Publication Year :
- 2017
- Publisher :
- International Union of Crystallography, 2017.
-
Abstract
- The title compound, C17H24Cl2, was synthesized in four steps from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from an essential oil of the Atlas cedar (Cedrus atlantica). The molecule is built from fused six- and seven-membered rings, and an additional three-membered ring. The dihedral angle between the mean planes of the cyclohexene and cycloheptane rings is 58.37 (19)°. There is an intramolecular C—H...Cl hydrogen bond present involving a Cl atom and the H atom of the unique methine C atom, forming an S(5) ring motif. There are no significant intermolecular interactions present.
- Subjects :
- crystal structure
β-himachalene
three fused rings
Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 24143146
- Volume :
- 2
- Issue :
- 3
- Database :
- Directory of Open Access Journals
- Journal :
- IUCrData
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.94a1a939d9784f87abcde3f35b51404c
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S2414314617004217