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(1S,3R,8R)-2,2-Dichloro-3,7,7,10-tetramethyl-11-methylenetricyclo[6.4.0.01,3]dodec-9-ene

Authors :
Ahmed Benharref
Lahcen El Ammari
Mohamed Saadi
Noureddine Mazoir
Moha Berraho
Source :
IUCrData, Vol 2, Iss 3, p x170421 (2017)
Publication Year :
2017
Publisher :
International Union of Crystallography, 2017.

Abstract

The title compound, C17H24Cl2, was synthesized in four steps from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from an essential oil of the Atlas cedar (Cedrus atlantica). The molecule is built from fused six- and seven-membered rings, and an additional three-membered ring. The dihedral angle between the mean planes of the cyclohexene and cycloheptane rings is 58.37 (19)°. There is an intramolecular C—H...Cl hydrogen bond present involving a Cl atom and the H atom of the unique methine C atom, forming an S(5) ring motif. There are no significant intermolecular interactions present.

Details

Language :
English
ISSN :
24143146
Volume :
2
Issue :
3
Database :
Directory of Open Access Journals
Journal :
IUCrData
Publication Type :
Academic Journal
Accession number :
edsdoj.94a1a939d9784f87abcde3f35b51404c
Document Type :
article
Full Text :
https://doi.org/10.1107/S2414314617004217