Back to Search
Start Over
X-Ray Crystallographic Analysis, EPR Studies, and Computational Calculations of a Cu(II) Tetramic Acid Complex
- Source :
- Bioinorganic Chemistry and Applications, Vol 2017 (2017)
- Publication Year :
- 2017
- Publisher :
- Wiley, 2017.
-
Abstract
- In this work we present a structural and spectroscopic analysis of a copper(II) N-acetyl-5-arylidene tetramic acid by using both experimental and computational techniques. The crystal structure of the Cu(II) complex was determined by single crystal X-ray diffraction and shows that the copper ion lies on a centre of symmetry, with each ligand ion coordinated to two copper ions, forming a 2D sheet. Moreover, the EPR spectroscopic properties of the Cu(II) tetramic acid complex were also explored and discussed. Finally, a computational approach was performed in order to obtain a detailed and precise insight of product structures and properties. It is hoped that this study can enrich the field of functional supramolecular systems, giving place to the formation of coordination-driven self-assembly architectures.
- Subjects :
- Biotechnology
TP248.13-248.65
Inorganic chemistry
QD146-197
Subjects
Details
- Language :
- English
- ISSN :
- 15653633 and 1687479X
- Volume :
- 2017
- Database :
- Directory of Open Access Journals
- Journal :
- Bioinorganic Chemistry and Applications
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.92052b411746d6aeeb29306c54b949
- Document Type :
- article
- Full Text :
- https://doi.org/10.1155/2017/7895023