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Dicaesium tetramagnesium pentakis(carbonate) decahydrate, Cs2Mg4(CO3)5·10H2O

Authors :
Christine Rincke
Horst Schmidt
Wolfgang Voigt
Source :
IUCrData, Vol 5, Iss 2, p x200165 (2020)
Publication Year :
2020
Publisher :
International Union of Crystallography, 2020.

Abstract

The title carbonate hydrate, Cs2Mg4(CO3)5·10H2O, was crystallized at room temperature out of aqueous solutions containing caesium bicarbonate and magnesium nitrate. Its monoclinic crystal structure (P21/n) consists of double chains of composition 1∞[Mg(H2O)2/1(CO3)3/3], isolated [Mg(H2O)(CO3)2]2– units, two crystallographically distinct Cs+ ions and a free water molecule. The crystal under investigation was twinned by reticular pseudomerohedry.

Details

Language :
English
ISSN :
24143146
Volume :
5
Issue :
2
Database :
Directory of Open Access Journals
Journal :
IUCrData
Publication Type :
Academic Journal
Accession number :
edsdoj.91a47070ab746b3ad9bafc63528eebf
Document Type :
article
Full Text :
https://doi.org/10.1107/S2414314620001650