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catena-Poly[[bis(nitrato-κ2O,O′)zinc(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ2N2:N2′]

Authors :
Xue Wang
Jin-Sheng Gao
Zhi-Yong Ding
Guang-Feng Hou
Source :
Acta Crystallographica Section E, Vol 66, Iss 6, Pp m700-m700 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

In the title compound, [Zn(NO3)2(C20H18N4)]n, the ZnII atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetrahedron defined by two O atoms from two nitrate groups and two N atoms from two ligand molecules. A distorted octahedron may be assumed when two of the symmetry-related nitrate O atoms, with Zn—O distances of 2.528 (2) Å, are added to the coordination environment. Another twofold axis, passing through the middle of the biphenyl bonds, is observed in the crystal structure. A chain along [101] is built up by the ligands linking the ZnII ions.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
6
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.90763fb1647c453595e6014f9a60f03a
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536810018738