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catena-Poly[[bis(nitrato-κ2O,O′)zinc(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ2N2:N2′]
- Source :
- Acta Crystallographica Section E, Vol 66, Iss 6, Pp m700-m700 (2010)
- Publication Year :
- 2010
- Publisher :
- International Union of Crystallography, 2010.
-
Abstract
- In the title compound, [Zn(NO3)2(C20H18N4)]n, the ZnII atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetrahedron defined by two O atoms from two nitrate groups and two N atoms from two ligand molecules. A distorted octahedron may be assumed when two of the symmetry-related nitrate O atoms, with Zn—O distances of 2.528 (2) Å, are added to the coordination environment. Another twofold axis, passing through the middle of the biphenyl bonds, is observed in the crystal structure. A chain along [101] is built up by the ligands linking the ZnII ions.
- Subjects :
- Crystallography
QD901-999
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 66
- Issue :
- 6
- Database :
- Directory of Open Access Journals
- Journal :
- Acta Crystallographica Section E
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.90763fb1647c453595e6014f9a60f03a
- Document Type :
- article
- Full Text :
- https://doi.org/10.1107/S1600536810018738