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[μ-1,4-Bis(1,2,4-triazol-1-ylmethyl)benzene]bis[aqua(pyridine-2,6-dicarboxylato)copper(II)] monohydrate

Authors :
Gui-Ying Dong
Cui-Hong He
Liu Tong-Fei
Xiao-Chen Deng
Xiao-Ge Shi
Source :
Acta Crystallographica Section E, Vol 67, Iss 7, Pp m944-m944 (2011)
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

The title compound, [Cu2(C7H3NO4)2(C12H12N6)(H2O)2]·H2O, displays a discrete dinuclear structure, in which the central CuII atom is five-coordinated in a distorted square-based pyramidal coordination geometry and the flexible ligand 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene adopts a bis-monodentate bridging mode linking the CuII atoms. It is further assembled by O—H...O hydrogen-bond interactions involving both the coordinated and uncoordinated water molecules. The latter exhibits half-occupancy.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
7
Database :
Directory of Open Access Journals
Journal :
Acta Crystallographica Section E
Publication Type :
Academic Journal
Accession number :
edsdoj.8f492f7049764680abd7a79064074aa3
Document Type :
article
Full Text :
https://doi.org/10.1107/S1600536811022756